Hexakis(2-aminopyridinium) di-μ6-oxido-tetra-μ3-oxido-tetradeca-μ2-oxido-octaoxidodecavanadium(V) dihydrate
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چکیده
In the title compound, (C(5)H(7)N(2))(6)[V(10)O(28)]·2H(2)O, the [V(10)O(28)](6-) anion is generated by crystallographic inversion symmetry and each of the five vanadium centres adopts a distorted VO(6) octa-hedral geometry. In the crystal structure, a network of N-H⋯O, N-H⋯(O,O) and O-H⋯O hydrogen bonds helps to establish the packing.
منابع مشابه
Hexakis(dimethylammonium) di-μ6-oxido-tetra-μ3-oxido-tetradeca-μ2-oxido-octaoxidodecavanadate(V) monohydrate
In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6-) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa-hedral geometry. Eight terminal O atoms are bonded to V(V) atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network ...
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